The dream of producing hydrocarbon fuels from carbon dioxide and sunlight is one step closer thanks to chemists in Europe who have made jet fuel from scratch in a solar reactor for the first time. Although the chemists only produced enough kerosene to fill a glass jar, they believe a full-scale solar concentrator could produce 20,000 litres of jet fuel a day.
The idea of extracting carbon dioxide from the atmosphere and converting it into fuel is simple enough. At high temperatures carbon dioxide and water dissociate into hydrogen, carbon monoxide and oxygen. The hydrogen and carbon monoxide mixture, known as synthesis gas or ‘syngas’, can then be converted into liquid hydrocarbons such as petrol or kerosene via the well-established Fischer–Tropsch process, which was invented by the chemists Franz Fischer and Hans Tropsch in Germany in the mid 1920s.
Unfortunately, the idea has suffered from two problems. One is that the dissociation of carbon dioxide and water only takes place at very high temperatures, typically above 2200°C. But the other, more difficult, problem is that the syngas cannot be tackled by the Fischer–Tropsch process until all the oxygen is removed as it is dangerously explosive.
Andreas Sizmann at the German thinktank Bauhaus Luftfahrt, together with colleagues in the EU-backed Solar-Jet project, solved the first problem of generating high temperatures by exploiting a high-flux solar simulator at the Swiss university ETH Zurich. Various methods have been tried to effectively remove oxygen from syngas, but the one settled on by the Solar-Jet team was the use of cerium oxide, or ceria. When heated to around 1500°C by the concentrated sunlight, ceria reduces to release oxygen gas, which is piped out. In the next stage, this reduced metal oxide reacts with carbon dioxide and water to produce hydrogen and carbon monoxide – syngas – taking up oxygen in the process. Finally, back in its original form, the ceria can be blasted with concentrated sunlight, reducing it once more and repeating the cycle.
The benefit of using ceria is that the oxygen and syngas are produced at different steps and can, therefore, be collected separately, enabling the syngas to be fed straight into the Fischer–Tropsch process. This was performed onsite by Shell, a collaborator on the Solar-Jet project and one of several oil and gas companies developing Fischer–Tropsch for the production of kerosene from syngas.So far the Solar-Jet group have only managed to produce a glassful of kerosene using the artificial sunlight, and carbon dioxide from a gas cylinder, with an average efficiency of 1.73%. Nonetheless, Sizmann believes it is a demonstration that will pave the way for renewable hydrocarbon fuels. ‘This is an extremely important milestone in the long-term process of developing a truly sustainable alternative fuel future,’ he says. ‘The process [draws] from virtually unlimited resources with no prohibitive cost “show stopper” in sight.’
Source: rsc.orgAdded: 6 May 2014